Description
Catalogue Number	100029
Synonyms	ACN, Methyl cyanide, Ethyl nitrile, Cyanomethane
Overview	LiChrosolv® hypergrade is accurately tested for LC-MS suitability, and meet all the requirements of modern LC-MS ionization methods (ESI/APCI - positive and negative mode). Thanks to their low level of ionic background and low ion suppression, LiChrosolv® hypergrade solvents provide high reproducibility and high ionization efficiency. The packaging material has been improved to meet LC-MS quality requirements perfectly.

Applications
Application	Acetonitrile hypergrade for LC-MS LiChrosolv®. CAS 75-05-08, molar mass 41.05 g/mol, and chemical formula CH₃CN.

Physicochemical Information
Boiling point	81.6 °C (1013 hPa)
Density	0.78 g/cm3 (20 °C)
Explosion limit	3.0 - 17 %(V)
Flash point	2 °C
Ignition temperature	524 °C
Melting Point	-45.7 °C
Vapor pressure	98.64 hPa (20 °C)

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H225: Highly flammable liquid and vapour. H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled. H319: Causes serious eye irritation.
Precautionary Statement(s)	P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal Word	Danger
RTECS	AL7700000
Storage class	3 Flammable liquids
WGK	WGK 2 obviously hazardous to water
Disposal	1 Strongly contaminated halogen-free organic solvents: container A.

Safety Information
Categories of danger	highly flammable, harmful, irritant

Storage and Shipping Information
Storage	Store at +2°C to +30°C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 1648 , 3, II
Declaration (transport by air) IATA-DGR	UN 1648 , 3, II
Declaration (transport by sea) IMDG-Code	UN 1648 , 3, II

Specifications
Purity (GC)	≥ 99.97 %
Identity (IR)	conforms
Evaporation residue	≤ 1.0 mg/l
Water	≤ 0.01 %
Color	≤ 10 Hazen
Acidity	≤ 0.0001 meq/g
Alkalinity	≤ 0.0002 meq/g
Al (Aluminium)	≤ 10 ppb
Ca (Calcium)	≤ 10 ppb
Fe (Iron)	≤ 10 ppb
K (Potassium)	≤ 5 ppb
Mg (Magnesium)	≤ 10 ppb
Na (Sodium)	≤ 50 ppb
Any further metal (ICP-MS)	≤ 5 ppb
Gradient grade (at 210 nm)	≤ 1.0 mAU
Gradient grade (at 254 nm)	≤ 0.5 mAU
Fluorescence (as quinine at 254 nm)	≤ 1.0 ppb
Fluorescence (as quinine at 365 nm)	≤ 0.5 ppb
Transmission (at 191 nm)	≥ 25 %
Transmission (at 195 nm)	≥ 85 %
Transmission (at 200 nm)	≥ 96 %
Transmission (at 215 nm)	≥ 98 %
Transmission (from 230 nm)	≥ 99 %
Suitable for LC-MS; Intensity of background mass peak based on reserpine (APCI/ESI positive)	≤ 2 ppb
Suitable for LC-MS; Intensity of background mass peak based on reserpine (APCI/ESI negative)	≤ 20 ppb
Filtered by 0.2 µm filter

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Acetonitrile Hypergrade 2,5 Lt (Asetonitril Hipergrad) CAS: 75-05-08